Band tail states are localized electronic states existing just below the conduction band or right above the valence band. They arise as a consequence of disorder. Thermal, structural, impurity, and/or compositional disorder can all lead to the formation of band tail states.

What is band tailing effect?

For small band tailing (γ < kT), the effect of band tailing is to simply broaden the luminescence peak. For systems with large band tailing (γ > kT), the luminescence shifts to energies below the nominal absorption band edge.

How do you calculate Urbach energy?

The equation for Urbach energy is given by a = a0 exp(E/Eu), where, a is the absorption coefficient, a0 is constant, E is the photon energy, and Eu is the Urbach energy. The Urbach energy is calculated by plotting ln a vs.

What is optical band gap?

The optical bandgap is the threshold for photons to be absorbed, while the transport gap is the threshold for creating an electron–hole pair that is not bound together. The optical bandgap is at lower energy than the transport gap.

How is TAUC plot calculated?

A Tauc plot is used to determine the optical bandgap, or Tauc bandgap, of either disordered or amorphous semiconductors. … Tauc plot

  1. r = 3 for indirect forbidden transitions.
  2. r = 2 for indirect allowed transitions.
  3. r = 3/2 for direct forbidden transitions.
  4. r = 1/2 for direct allowed transitions.